I have determined I need to build a UVLO using a Zener reference. I have breezed through CURRENT SOURCES & VOLTAGE REFERENCES by Linden T. Harrison and noticed that the flattest tempco of a Zener is around 5.5V. This jibes with what I have learned prior. Zener voltage references also add a pn junction and the Zener is set to have +2.1mV/C TC. For reasons I have not researched, this combination operated at a particular current has a near zero TC and results in a total voltage of 6.3V. However it seems to me that the Zener itself could be set to have a zero TC alone. My guess why this is not the common method is that this doping level is more sensitive to process variation than the level that has +2.1mV/C. I just don't know
Now, I am going to have to indirectly ask questions of the technology group to determine why the Zener we have is set to 6.3V. I have a suspicion that someone told someone that the zero TC voltage is 6.3V without understanding that this includes a Vbe! ARGH! Monday is going to be fun.