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Why can't high frequency signals be transmitted through ordinary wire?
This is due to "Skin Effect". The Skin Effect is tendency of high frequency current to be highest at surface of conductor and decay exponentially towards centre.
https://www.ultracad.com/articles/skin effect.pdf
Skin effect - Wikipedia, the free encyclopedia
In the end, it's a flow of electron.Then sir, pls tell what kind of wires can be used.
Also, I would like to know how do signal travel in wires/waveguides/cables..
ie. do they travel as EM waves or like beam of electrons [as in, a DC current flowing thru a copper wire].
They're not. READ the links.