You can find the description of each single pin in the table at page 5.
The capacitor C1 and C2 are used by the IC to double the voltage so they are floating with repect to ground and Vcc. As you said, they have to be connected from C1+ to C1- and from C2+ to C2- (pins 1,3,4,5 for ICL3232).
The capacitors C3 and C4 are used to stabilize the +5.5V and the -5.5V generated internally to the IC by the doublers. they have to be connected from V- and ground (C4) and from V+ and ground or Vcc (C3), as you like. Note that the C3 polarity is always with the positive lead to the V+ pin since it is alwys more positive than ground and Vcc. Ic pins are 3 and 7.
The capacitor from Vcc to ground is used to stabilize the Vcc you use to supply the IC. Also this capacitor has to be placed close to the IC.
About the orientation, the dot is placed on pin 1.