Barry, My statement is somewhat confusing. The best definition for Ts is the temperature of the soldering point, that is where the hottest lead touch the PCB. They use the temperature of the hottest soldering joint (for bipolars where the collector is directly atached to the collector lead, the collector lead is the hottest).
In the image of the datasheet, they specify: Ts< 71 degr, dissipation 330 mW (first line). So there is 150-71 = 79 degr drop between the junction and the solder point at the PCB (assuming 150 degrees maximum junction temperature). So Rthjunction-solderpoint = 79/330mW = 240 K/W.
To find the junction to ambient resistance, you need to know Rsolderpoint-ambient, and that depends on substrate type, substrate thickness, copper thickness and size, additional vias, etc.
So the overall thermal resistance is the sum of Rj-s and Rs-a (s = solder point, a = ambient, j = junction).
Manufacturers generally provide data on how to estimate Rs-a, as measuring the solder point temperature requires a thermal imaging camara with very good resolution (I don't have that).
hopefully this makes more sense to you.