report_timing
report_timing shows the most critical path (it may show the most critical path for each clock group)
critical path is defined as worst negative slack, which is the difference between data required and arrival time. When you time with latchs, time borrowing may happen and your required and arrival times will be the same and slack will be 0. If this is the case, this path isn't neccessarily your most critical path. You can check more paths like this:
report_timing -path end -max_paths 100