Hi,
I'm not sure. My assumption:
Max working voltage is limited by the power dissipation.
V_w = sqrt(P x R)
This is for DC current or voltage. But if it is pulsed you may increase voltage..but not infinitly.
Additionaly imagine a very high ohmic resitance..maybe 10M..and a max P of 0.25W...this gives about 1600V ..
But there will be some voltage where a spark jumps from one contact to the other...independent of resistance value.
For sure this depends on age, dirt, humidity, flux residuals...
But I assume this is the "limiting voltage"..
Klaus