If u are using spectre as simualtor, then u can find capacitance at DC and transisent.
Capacitor is open to DC -- capacitor cannot pass a DC signal however u can still charge a capacitor using a DC signal. capacitance is ability to hold charge.
CapTab in Transient in Spectre . choose tran analysis -> options -> click on misc tab and click on captab checkbox , then click on output tab and enter time u want the cap to be calculated in infotimes entry.
if u dont enter infotime the capacitance will be computed for the last tran time step. u can enter 1 or more time point in infotimes seperated by a "space". u can view the result using capacitance table under result->print->capacitance table