To make an ultrasonic transmitter and receiver you need no PIC microcontroller. You need e.g. a NE 555 timer, make an ultrasonic generator, and tune it to the frequency printed on the transducer. Some are made for 24 kHz , others for 40 kHz (smaller diameter).
For a receiver, you need an audio amplifier tuned again to the same frequency. You can use an opamp or another audio amplifier, again tuned to 22 or 40 kHz.
Depending on the purpose or how you intend to use the transmitter and receiver, you can use a programmable device to evaluate the receiver output amplitude, pulse delay, etc.