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To add to the discussion, you also need to ensure that the L1 choke that the datasheet recommends does not saturate for the new output voltage setting.
My calculations show that there is a small increase in inductor peak current with 5V output compared to the 3.3V output (for same output maximum load current). Also Vin_min will no longer be allowed to be 4.4 V, this being a buck topology.
Regards