@shamikrudra,
I made double sided pcb at home. When I did this, I didn't know about toner transfer method.
Process I followed was very critical. I printed both side of the pcb on my inkjet printer, made a 1:1 negative film thereof from a shop who make films of artwork for screen printing. Cut the double side copper clad board (CCB) in size, activated both side of it with negative photo-resist, dried, and kept it in a light proof packet.
Then held both top and bottom film against light to synchronise all vias and corner marks, and closed along 3 sides of it with transparent cello-tape - in the form of an open mouth envelope. Put the pre-activated CCB into it and placed this CCB filled envelop between two pieces of glass like a sandwich - clipped tightly. This process was done under yellow safe-light (night-lamp) in a dark-room. Kept the hole combination in a light-proof large envelop - made of black thick art paper.
Now exposed both side of this sandwich in direct sunlight for 45 seconds to each side, keeping it on the black envelop so that the other side may not get over-exposed. Put the sandwich back in the black envelop.
Then back in the dark-room developed the CCB with die-developer. Now the exposed places darkens and turn to black, stays on the CCB as mask, and unexposed photo-resist dissolves in the developer - where copper became bare again. Masking was ready, washed and dried the CCB without damaging the masking.
Etched this CCB in Ferric-chloride and get the PCB.
I was unable to plate the hole-wall of the via with copper, because I didn't find conductive ink.
The photo-resist I used is meant for making block for printing works. This blocks are like huge solid barrel used to print nice color photos on millions of poly-pack, pouch that we use and throw away everyday.
Though this process is very accurate, but is costly and critical at the same time for making one or two pcbs for the prototypes. I won't suggest to follow this way of making pcbs unless very accurate and high density component population is required in a prototype. Use toner-transfer instead
I shall try to find those things that I used for the process and upload the photos that may clarify the steps.
That's all. Thanking you.
p55xp.