Hello
The nominal voltage of a NiCd cell is 1.2V. So I think that you used 8 cells in series to make a battery pack of 9.6V.
The voltage of any healthy cell may range from 1.1V to 1.65V. So, the overall voltage of battery pack may range from 8.8V (minimum voltage during discharging) to 13.2V (maximum voltage during charging).
You Have to stop the charging if the pack reached the maximum voltage. as exceeding this voltage is very harmful for the cells and it may cause chemical problems.
as you might know each cell has an internal resistance. So the Apparant voltage V can be calculated from the equation :
V=E+I*R
where E is the internal voltage and R is the internal resistance. when I=0 , V=E
you dont have to care about the value of E during charging , as long as your batteries are healthy.
To keep you cells healthy , dont ever over charge them or deeply discharge them ! you have to charge/discharge the whole pack together to keep the cell as identical as possible. DONT work on any cell individually as the mismatching between cells will lead to balancing problems.
I wish this info is benefiting for you. fell free to ask any question
Ahmed Salah