The answer to the first question corresponds to v_naren's solution but the following solution also accounts for potential differences in the index of refraction for different glass types (an index of refraction of 1.54 for glass is common, but not all glass has an index of refraction of 1.54). Since the reflected angle was given, and the index of refraction can be extracted, it is prudent to explore that possibility.
The critical angle can be calculated by taking the inverse-sine of the ratio of the indices of refraction of the reflected and incident mediums.
Since the incident angle is 33 degrees the reflected angle is therefore 33 degrees. The problem states that the reflected and refracted angles are separated by 90 degrees. That leaves a reflected angle of 57 degrees with respect to the plane of the glass.
However, for the law of refraction shown below, where Ni here refers to the index of refraction for the incident and Nr for the reflected material, the angles are relative to the normal (perpendicular) to the glass.
Therefore Ni = 57 and Nr = 33.
Ni * sin(i) = Nr * sin(r)
Air has a Ni of 1.0.
Therefore Nr= (Ni*sin(i)) / sin(r) = 1*sin(57) / sin(33) = 1.5399 = 1.54
Then the ratio of Nr to Ni = 1.54. The inverse sin of 1.54 (and the critical angle) is 40.496 degrees or 40.5 degrees.
The second question is vague. What does "optically dense" mean? Only if it correlates to index of refraction can the question be answered. But if so, as v_naren stated the critical angle only exists for a transition from a a higher to lower index of refraction. Otherwise in the formula above you would be taking the arcsine of a number greater than 1 -- which is a complex number.