Hello
the step size defines the resolution, the less step size mean higher resolution
Resolution=V full scale/ 2power -1= step size
the full scale voltage is the maximum input analog signal amplitude
n: number of digital bits and also we call it resolution
so according to your application you can decide the resolution. for general data signal processing the good resolution is 8 bit and more.
if you are really sure that you want 0.1 step size, put this value in the above equation, it will give you a resolution of around 3 bit, now do you think 3 bit resolution is sufficient for your task????? it is now up to you