Think of Zener as being a controlled low voltage avalanche. The junction is doped to deliberately permit the current to start flowing at the desired voltage. An avalanche diode usually runs at higher voltage and the effect is similar to the junction breaking down form excesive voltage. Provided the current is limited to a safe level, the avalanche is not destructive and can be repeated. What is 'special' is the speed at which the breakdown occurs which can be used to advantage when fast edged pulses are needed.
The diode does not produce any voltage whatsoever so person #1 gave you wrong advice. Person #2 is correct but to generate any high voltage (apart from here being much more efficient ways) you have to use the speed of the pulse in a controlled manner, usually a step up transformer. Bear in mind that pulse may only be a few uS long so as a power supply source they are useless.
Brian.
To my knowledge, Zeners are P/N junctions with doping allowing to "tune" the reverse breakdown at certain voltages. saw 3 V Zeners as well as 67V ones. Some exhibit a "bent" in I/V curve which is used as a negative resistance, to generate noise from several Hz up to ~50 MHz.
Avalanche breakdown can be seen in almost an P/N junctions, and usually destroys the junction. Using a series resistor to limit the current, a diode or a transistor generates noise or pulses of the amplitude corresponding to the breakdown voltage.
Special P/N juctions were made to generate a negative resistance usable up to >100 GHz. The junction should be coupled to a high-Q resonator to generate a "clean" spectrum, still it is noisy.
Another P/N junction type, usually e-b transistor junctions and specials with a "guard ring", have breakdown voltages ranging from 5 to 35 V, and can be used as wideband noise sources, up to ~90 GHz. Spectrum strongly depends on the current, my noise sources of this type are nice and flat with 5 to 15 mA.
For pulse generators try to use ordinary switching transistors with c-e breakdown 50 V, use a large collector resistance like >10 kOhms. With a coaxial-cable section used as a delay line, collector voltage pulses are nice and >50 V upon triggering by e-b voltage pulse.
Many years ago, H-P issued a white paper on avalanche-diode pulse generators, used in their wide-spectrum pulse generators.