If you are making your own netlist (without the schematic entry)
You have to use a "dot command" like
.print dc v(1)
This will print the value of v(1) in the corresponding *.out file
.print tran v(1)
This will print the value of time and v(1) in the *.out file
*.out file is an ASCII file which can be read by a text editor.
If you are using PSpice Schematics, just simulate the circuit and
display the output using probe. Then just click on the label of the waveform.
That should be located on the lower left side of the waveform panel with symbols in front of it. When you click on the name of the waveform (for example V(1)) it should have a red color. Once this happens just use Edit > Copy. Then go to a text editor or a spreadsheet and do Edit > Paste. You should see the waveform data.