I suggest that you use a dual pot. To use a single pot, you'll have to include some extra circuits to translate the movement of the single pot to two channels. It's possible, but in my opinion, it's not worth the hassle for such a simple amplifier.
By the way, I also suggest that you change the output coupling cap from 100uF to at least 220uF, preferably more. With an 8-ohm load, 100uF will give a -3db low frequency cut-off at 200 Hz. If you intend to listen to music with a reasonably good headphone, roll off at 200Hz will result in poor bass reproduction.