Power handling is limitated by almost 2 dangereous fenomena:
Joule effect, related to the specific loss (dB/m) and the heat dissipation.
Corona effect and Voltaic Arc, related to the voltage and the dielectric "rigidity".
Connectors are often filled with air dielectric lines wich are more sensitive, than the dielectric, to the spark.
Because the Voltaic Arc may be destructive, it's is not suggested to calculate, knowing the geometry, the max voltage. In this case a safety, and arbitrary coefficient is applied by manufacturs.