Thank you, everything is clrearer by now!
Actually, I first simulated some capacitors in my library, but the leakage changes regarding the voltage applied to the capacitor, but also the capacitance change! On the plot "Capacitor_impedence_vs_voltage", I simulate a DC ramp from -3 to 3V with a sinewave of 1mV. We can see the leakage (average current) never constant, and the capacitance (corresponding to the peak to peak current) changing but almost constant after 1.5V. Nevertheless, after 1.5V, the capacitance measured is different from the settings! Any idea what kind of cap it could be? For me it's also polycap.
Anyway, I abord these capacitances and found the right one you suggested. The plot for the P one is presented and it could be quite constant if the voltage doesn't change too much. I also simulated the P and N in parallele and got this last plot. The difference of the capacitance is 11%! As my project is for measurements, I'll keep the design with MIM capas, but I'm not sure that my boss will accepte to buy the metal mask!