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Kindly tell me about the number of electrons in the valence shell of aresnic,gallium,silicon and boron, then I will answer your question
To become a compound, each element needs to have eight electrons in its valence shell. Now if arsenic reacts with an element whose valence shell contains three electrons then 5+3=8, it will become a compound same is the case with any other element e.g.
gallium=3, other element=5 (it will become a compound)
silicon=4, other element=4 (it will become a compound)
boron=3, other element=5 (it will become a compound)
However if arsenic combines with an element that has 4 electrons in its valence shell, we will be left with an extra electron (5+4=9) and if it reacts with an element that has 2 electrons in its valence shell in that case we will have deficiency of one electron called a hole (5+2=7), get it?
Other elements will behave the same way
So when aresenic and gallium combine (5+3=8) it becomes a full compound but when silicon and boron combine (4+3=7) there is still vacancy for one more electron called a hole