I doubt it will work as expected.
Firstly, the base resistors are FAR too low in value, the maximum current from a single IO pin is 25mA and the total for all the IOs combined must not exceed 200mA. The resistors should keep the current well below that.
Secondly, using an emitter follower configuration means the emitter (and therefore your output voltage) will always be about 0.6V lower than the base voltage. Given that the IO pin voltage will drop considerably under high current, you will probably only achieve quite a lot less voltage at MP4 and MP5. You will probably find the current available at the outputs is quite low too.
If you need high output current:
I would suggest you ground the emitters, connect the collectors to the outputs and make pin 6 of MP5/MP5 go to VCC instead.
If you need logic voltage outputs:
Ground the emitters, add a pull-up resistor between each collector and VDD and leave pin 6 at VSS. Note that this reverses the logic state so your software should output a '1' instead of '0' and '0' instead of '1'.
You should also add decoupling capacitors between VDD and VSS and be careful not to make VCC too high, it must be more than about 7.5V for the regulator to work but if you go too high there is a risk of the transistors back feeding to the PIC.
Brian.