Well I'm not going to redesign it for you but I will give you some clues:
1. completely remove Q1/R5 and everything before it. Feed the 14V directly across C1.
2. completely remove Q3/D4 as they do nothing, if they ever did start to conduct they would burn up immediately.
3. increase C1 to maybe 1,000uF
4. remove U2/R6/R7 and replace them with a 7805 (or 78L05) fixed regulator instead. This will let you power the PIC with 5V as well.
5. remove C4, I'm not sure what it is supposed to do.
6. increase R13 to say 470 Ohms and add a capacitor across it, 100uF or more.
7. there is no feedback path to regulate the output voltage, add a potential divider across the output and feed the center back to a PIC ADC input.
8. drop the values of R8/R9 by a factor of 10 times at least. They are only there to monitor the battery voltage, with such high values all you do is make it more prone to noise pick up.
Even then, you must remember that this is a boost circuit, even if you turn the PWM off completely, the output will not go lower than the battery voltage less the drop across D3.
Brian.