There are different MSOP packages in the Altium designer PCB libraries.
The first point is to check if 0.45 pad width is appropriate for the respective part. It might be for some power devices that have relative wide pins.
Secondly, the solder mask finish depends an actual expansion rules. Now it's apparently about 0.1 mm, which mostly isn't acceptable for high density boards. They require 0.075 down to 0.05 mm.
There's however a minimum solder mask width that can be reliably structured. Below this value, solder mask strips might break and foul the PCB surface, particularly SMD pads.
So all in all, it depends on available PCB technology. With low technology, it may be necessary to omit any solder mask feature between small pads, despite the risk of solder bridging.