You should use an oscilloscope to evaluate the output PWM signal.
SG3524 is a closed loop controller. It will make the necessary effort (PWM's duty cycle) to make the two inputs of the error amplifier (pins 1 and 2) to be equal. Usually we put a fixed voltage at the non-inverting input, and a feedback signal at the inverting input. If the feedback signal is lower than the reference signal, the duty cycle will be increased until it reaches maximum value (50% for each output). If the feedback is greater than reference signal, the duty cycle will be decreased, and can be zero if you use fixed signals. In practice, a reduction in duty cycle makes the output voltage to decrease, which in turn forces the duty cycle to rise again, until the circuit reaches its steady-state.