As far as I know, NoiseCom noise generators come with an ENR table showing ENR over a frequency range. With an attenuator inserted to the output, you have to include corrections of ENR as a function of loss and attenuator temperature.
Measuring ENR is possible with a spectrum analyzer but it must be well calibrated, best to a good termination at a known temperature.
Find Agilent document on noise measurement with all details.
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Better than a spectrum analyzer is to use a good power meter which usually has a better accuracy and a better resolution of a power level.
Can you indicate what your task is? Frequency range, bandwidth, noise figure of a tested device...