maybe possible, it depends on the motherboard of the PC, you would need to use a powered USB hubs for this.
A better option would be to use a RS 485 network. For this you only need one COM port connected to a RS 485 adapter (there are many available online), the network is connected to a RS 485 transciever IC, such as the SN75176. The transciever then sends/receives the data to the PIC serially on TTL levels.
With this option the PC can individually address each micro-controller and read data. You need to implement a suitable protocol for transferring data in packets. Try searching the internet for more on RS 485 protocols.
thanks
a