No, I think if you want 3 sigma yield, your VCOmax should be 1.65+/- 50mV because the 50mV is equal to 3 sigma, while 1 sigma is 16.6mV. Either way your simulations show you are well below these limits.
When I said sigma saturation, I meant that you run, say 100 runs and get some sigma, then run 200 runs and get somewhat different sigma, then run 300 runs, 500 runs, etc and as you increase the number of runs the sigma changes less and less until it doesn't practically change anymore i.e. saturates and this will be kind of the number of MC runs that are giving good results. But this is just for experimental purposes. I think 200 runs already captures most of the statistical variations in the circuit. The rest is just some small adjustments.