Hi,
lowering resitor value: If the delay is ok for your application, then don´t change it.
If you lower it, then current increases. TVS clamps to 16.8V, VCC is 2.5V. Difference is 14.3V. subtracting 0.5V of BAT54 then at resistor is 13.8V. with 100R you get max 138mA. An ESD pulse is short in time. maybe 10us.
This current pulls up VCC with it´s capacitors: Max Vcc voltage is 4V, difference is 4-2.5V=1.5V. with 138mA, 10us, and 1.5V this gives a min. capacitance of about 1uF. So you need at least 1uF of VCC capacitance.
I recommend to use at least 10uF in total of all VCC capacitors.
I´d say its safe to lower it to 100 ohms.
****
Yes, LWL is german, FOC is english = FiberOpticalCable.
For industrial solutions i use HFBR types of AVAGO. It´s easy to use, for prototype you can cut the FOC carefully with a knife, or buy made-up cables.... There may be cheaper solutions.
You may also consider IR: IRDA, or remote control hardware...
Klaus