Hi,
Electrolytic capacitors usually are boxed in a aluminum cup.
The aluminum should prevent the elecrolytic from drying out, so only the top and the bottom - where no aluminum is - of the capacitor will be responsible for drying out.
Electrolytic capacitors have a safety vent. I don't think it's a good idea to modify this safety feature by potting the capacitor.
With an automotive application I've heard that even an air bubble in the glue underneath the capacitor (for fixing it) caused some problems. It had to do with some enclosed humidity within the bubble. I can't remember exactly what happened. If I remember right the prevented the air bubble by using vaccuum..
All in all I don't think that potting will reliably extend lifetime of an electrolytic capacitor.
You have to consider negative side effects.
Klaus