KamalS
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Direct Laser Imaging, I believe, not cutting ?
If you do want to try that, you may consider using the laser to expose a positive (or negative) resist, then develop the image and etch in the usual way. That avoids using a high powered laser, reflections (as mentioned above), and melting/resolidification.
If you do want to remove the resist, I would suggest an approach like is used with PCB milling. That is, you only photomill the isolations, not large open areas. A resist that would be vaporized quickly without appreciable melting would probably be best. I would consider something like a clear acrylic -- like a thin layer of cured super glue, nitrocellulose, or plasticote.
For Plasticote, try any auto parts store. Solvent-based model airplane dope (if you can get it in SoCal) may also work. There are two classic versions, nitrate and butyrate. The nitrate is "tauntening" and is basically a nitrocellulose. I think you will have better luck finding these finishes in automotive and hobby stores rather than in big box home centers. It is the pigments in paints that I think would be a problem. Krylon is another brand of clear finish to look for. I vaguely recall seeing it in a home center.
As for working in the dark with photoresists, that is not necessary. They are generally quite safe with dim incandescent light. I would avoid bright sunlight and white fluorescent lights. The commercial products contain a photosensitizer that makes them work with light in the near UV and violet (about 400 nm) region.
I occurred to me that the typical photoresists might burn off cleanly with your laser. For example, if you started with a positive resist board, you could burn away those areas of the resist that you want to etch. After etching, the remaining resist could be easily removed with 0.5M NaOH or other strong base. That way, you would avoid having to use organic solvents to remove a lacquer or paint. You would not have to worry about light, since both exposed and unexposed resist would be resistant to acidic etching solutions. (I am assuming as a hobbyist, you use an acidic etch.)
I use Injectorall, which is available from DigiKey (digikey.com). M.G. Chemicals has its branded product, which it sells directly and through Mouser Electronics (mouser.com). Jameco may sell the same product (jameco.com). There used to be a liquid spray you could use for DIY. For your initial experimentation, I would recommend against that. The coating on commercial boards is quite uniform, which should help for laser ablation. A third product by DuPont is more for commercial users. It is sold as a sheet, which must be laminated to the PCB, thus adding additional complexity and chances for problems.
I probably wasn't clear in my afterthought on using a photoresist. It won't matter whether it gets exposed to UV or not. It is not being used because of its photosensitivity, but because the resist lacks pigment (they may contain a clear organic dye) and is probably easily ablated with laser. Whether exposed or not to UV, the photoresists I am describing are removed with strong base. The developer is simply a weaker base or lower concentration of strong base than is used for removing all resist at the end of the process. You can also remove it with acetone, if you prefer.
Whatever you use, try to get something that is crystal clear -- you are using IR, right? I am a little surprised that Krylon left a residue. Clear acrylic enamel might be worth a try, as would clear polyurethane. The problem with enamels and urethanes is removal from the copper areas to which you need to solder after etching. Lacquer and dopes would be removable by solvents like acetone or MEK; cured enamels and polyurethanes would be more resistant to solvents.
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