With Monte Carlo you might have to run 30-100 simulations before you got a good estimate of the standard deviation (SD) due to random mismatch. On the other hand, DC match is a sensitivity analysis that is much like a noise analysis. It will give you the SD in a single simulation, making it very useful for large circuits. The downside is that you only get results for DC parameters like offset voltage. If you want to investigate things like transient settling times you would need to use monte carlo.
So... dc match is the best way to get the SD for Dc parameters, but it won't work for other things.
rg