For a variable output voltage which still maintains constant output power, the highest output current will occur at its lowest output.
Having said this, a bit of advice:
if you are serious about learning how to design a SMPS using your own discrete, you must invest in a good reference book. The requirements for a good design are too many to simply list on a forum post. Choosing practical inductor and capacitor values are the simplest parts of a SMPS design. Choosing the proper main switch drive, and most importantly control-loop stabilization, will be the next and most significant challenges. Not counting thermal management, snubber design, noise, etc.
There are many good books, but to me Switching Power Supply Design by Abraham Pressman and Keith Billings.
Many people also like Switch mode power supplies by Christophe Basso.