circuit simulator to extract capacitance
A less formal method (compared to the proposed by elek_fyc), is put the 2port s matrix into a linear simulator (ADS, Harmonica, MWO Genesys, etc), then short port 2 to GND, now you have an 1 port circuit. analyze and plot s11 in R+jX. format.
The imag. part is the reactance.
Give me the possibility to add a short note about real part: The equivalent Series Resistance. For my opinion, the typical accuracy of VNA measurement is not sufficient to get accurate knowledge of tand (or Q or ESR)