How do I go about choosing which transistor type (i.e. nmos2v, nmos2V_dnw, nmosmvt2V, etc) to use for a particular circuit? Is there a particular rule?
There should be 2 pdf documents in your PDK - one about SPICE simulation of devices for high frequencies (RF) and another one - for lower frequencies. They contain all info that you need.
In brief:
nominal device - transisitor with normal threshhold (smth around 0.4 V as far as I remember, it also slightly depends on the size of the transistor)
medium - low Vt transistor
native - zero Vt transistor
These 3 models of devices are for low freq. For igh freq there's just one type of transistor - rf (although its model is more complex)