It depends on your wiring. Remember the wiring will have inductance, so at some frequency this forms a resonant circuit with your capacitor. To get decent accuracy, you need to measure well below the resonant frequency.
I'll leave you to do the math. I don't remember the rules of thumb for nH per inch of straight wire or inductance for a given loop area etc.
Actually, it's probably easier to skip the math and do this by trial and error: Take a capacitance measurement at one frequency and another measurement at double the frequency. The answers should be similar. If they're wildly different, you're too close to the resonant frequency.
Depending on what equipment you have, it may be easy to find the resonant frequency e.g. by doing a sweep of impedance vs frequency.
In any case, it would be a good idea to minimize inductance - keep wires short and avoid loops.