I've used a variety of lead free solders both for production repair work and hobby projects. Lead free alloys require higher temperatures and stronger fluxes and strip the plating off of your iron tips much faster than lead alloys. I prefer a 62% Tin, 36% Lead and 2% Silver alloy. It's much easier to work with and produces clean, strong, shiny joints that are easy to inspect. I only use lead free when required and charge a premium for it.
Glutaric and adipic acid fumes from the fluxes used with lead free solder are a significant cause of occupational asthma. You can use a fume evacuation system but most benchtop devices merely redirect and dissipate the fumes in the room.
The best way is to extract the fumes, mask is not a good solution for long term use.
The fluxes used for soldering are probably a bigger health risk. I just use a small fan that blows air from one side of the work bench to the other. The flux smoke wafts upward, but the fan blows it to one side before it reaches my nose.
"The last Tommy", first world war veteran died a couple of years ago at the rather premature age of 115 years. He had been working with lead all his life as a plumber.
Don't see the problem my self.
Frank
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