Hi,
1:10000 dynamics is huge.
Maybe with a high quality geard pot.
0V really means 0mV? Mind: some pots can't go down to 0.00% nor to 100,00%.
Also there will be some "wiper impedance" which may cause additional errors.
And pots may drift...and drift by thermocouple effects..
There theoretically is an infinite resolution, but the useful resolution my be a mechanical problem, how much time you want to spend for adjusting it and how long you want it to keep the value within a given tolerance.
I guess you need to read datasheets, read application notes from pot manufacturers and/or contact pot manufacturers.
Klaus