Looking at your requirements, Pspice seems to be the better option for following reasons.
-- Firstly Pspice 16.6 version has TCL interface open, where you can play with the database and do lot of post-processing in TCL.
-- Pspice has powerful waveform analysis features. For example cursor lets you know the y values of all traces/plots at particular x value. Moreover you can quickly navigate to local/global maxima/minima of traces. Can quickly create measurements.
-- Pspice supports co-simulation with MATLAB
-- Only Simulator for which most of device manufacturers provide their device models.
-- Provides various advanced analysis. Apart from Monte carlo/Worst case analysis, Stress analysis (called smoke), Optimizer (for design/parameter optimization), Parametric plotter etc.
-- Well integrated with capture schematic entry and Allegro layout.