Yes. you should be able to simulate flyback transformer in PSpice.
DO you have design parameters available with you? based on that one can model the transformer model
Let's take a example where Flyback primary is 1mH, turn ratio is 1:2, primary and secondary winding resistances are 1m & 2m ohms respectively
Model would be
.subckt FLBTR 1 2 3 4
Lp1 1 2x 1m
Rp1 2x 2 1m
LS1 4 3x 4m ; Primary inductance * turn ratio *turn ratio
RS1 3x 3 2m
K1 LP1 LP2 1
.ends
Connect Pin 1 as primary + terminal
Connect Pin 2 as primary - terminal
Connect Pin 3 as Secondary + terminal
Connect Pin 4 as Secondary - terminal
Hope this helps.