Easiest would be to take one of the diodes that -is- supported,
copy its cell & underlying views to your own custom library
(unless you have write access to the PDK installation, which is
unlikely unless you are your own sysadmin). It's likely that the
photodiode is one of the usual junction combos plus a little
art. So pick the closest.
There's your symbol, for the name-changing. You can go figure
out netlisting re-pointing and so on, and get to where a placed
"photodiode" will run right in simulation.
Layout extraction probably means editing extract rules, and that
in turn may need layout features added or touched up (like if
devices are recognized by fancy logic and layers, not a simple
text tag). Probably have to add the rules for the photodiode,
again by copy-and-modify.
But before you get started down that road you might place a
layout instance and see what, if anything, extracts. That would
be an Easy Button. At least, relative to starting from nothing or
from something that's way unlike.