Most likely you will have to "supplement" the foundry PDK
with some hand-fitted models. I've done this with zener and
resistor elements (lvsIgnore='t') hand fitted to TLP 'scope
data (transmission line pulser, simulating ESD). I had to
build the TLP myself, used a spool of coax, a 100K feed
resistor, a 39-ohm output resistor (trying to get roughly
50 ohms total loop, including the clamps under test) and a
mercury wetted relay. A 1 ohm sense resistor in the return
and two 'scope probes will give you the I, V data you need.
I is voltage across the sense resistor, V is differential
voltage across the part. Drive the relay and trigger the 'scope
with a standard pulse generator.
To get 100V I had to stack every supply in the lab, but a
Variac and rectifiers would do as well. Without the HBM
series resistor you should be able to get past a couple
of amps, equating to a couple of kV ESD threat (kV = amps*1.5Kohm).