When you put multiple capacitors in series, the voltage across them divides according the the impedance - just like for resistors.
If you put your 2 capacitors (50V, 10uF) in series, ideally the network will have a capacitance of 5 uF and a voltage rating of 100 V. Ideally.
BUT, this is bad practice because the voltage distribution will change depending on the capacitance. For example, if the capacitor tolerance is +/- 25%, then one capacitor could be 7.5 uF and the other could be 12.5 uF. Now your network has a capacitance of 4.68 uF and if you apply 100 V across the network, the 12.5 uF capacitor will get 37.5 volts and the 7.5 uF capacitor will get 62.5V. So in this case you really have to use capacitors with a 62.5 V rating for an effective 100 V network rating.