Sir,
As you said , I agree with you. Even though what ever the SMT component values with their tolerance value are available in the ADS SMT library, Some values are not available in the real world. What ever real world existing values we used for the our design, it may give good results, but that component may not available in the SMT library. For example, 5.1PF with 0603 series is available in the real world, but the same 5.1 PF with 0603 series may not be available in the SMT library, nearer 5.6PF with 0603 may be available. In that case , mismatching of the real world value and the SMT library value, what decision we have to take. Either we have to choose the nearer value 5.6PF with 0603 series or we have to drop that value, whatever existing in the SMT library value, those values we have to search in the real world.