I think your circuit will work. I have used zener diode for similar protection before.
If your circuit can tolerate a little higher than 3.3V, I recommend to use a 2.6V zener. Near 3.3V (~2.5V across the zener), the zener starts to conduct depends on the tolerance of your zener. That means you have an extra "equivalent resistor" connected in parallel with the 10k pot. So your 3.3V setting may not be accurate. If you increase your zener to 2.6V or even 2.7V will give you more margin.