I would not use a coupled inductor if I were you, but it will work. You situation is just about ideal as you have identical output voltages (and currents I presume) and I assume the same type of output diodes. Problems start arising when you have two different output voltages, one with a Schottky diode and another with a fast recovery. Invariably the one voltage is not an integer multiple of the other so the turns ratio is not ideal. Under these conditions they should not be coupled too tightly.
In the interest of getting the product out the door in a reasonable time I would opt for separate output inductors and refine it if I have the time later. Depends on you situation I suppose. I try to minimise risk.