The efficiency of conversion from 5V to 30V can reach roughly 70-75% what at 8A (30V) output will require ≈70A@5V (350W) and no commercially available ATX (even 500W) can deliver that ..
8ampos at 30 volts means 240watts. converted will take nearly 60 amps at 5V
I don't think your concept would be feasible
I have a dobt
is that 8 amps On 5V line?