Hi,
Not exactely related to your problem:
my recommendation:
If you need a comparator, then use a comparator
if you need an opamp, then use an opamp.
Why:
An opamp is designed to regulate it´s output in a way that the difference voltage of Vin- and Vin+ is about zero.
There are a lot of opamps that have problems when differential input voltage is more than some 100mV. (latch up, extended delay, even phase reversal = output swings to the opposite side than expected)
An comparator is designed to handle large differential input voltage without problems.
Klaus