For safety reasons you MUST have the CRO chassis earthed. If you now trigger the beam from one phase, by using a 10:1 probe from the reference phase to the "Ext. trigger" in socket with its earth to any piece of earthed metal work. Now youselect "Ext trigger on the CRO and the CRO sweep is synchronised to the reference phase. Now select the "A-B" option on the Y amp, put both the A and B amps to 50V/Cm, use a 10:1 probe on each amplifier. Stick the A probe on the reference phase (no earth)and the B on another (no earth), mark on the graticule the positive, zero and negative transitions of the waveform. move the B probe to a different phase (no earth), measure the time difference to the reference - this is the phase difference. Move the A probe to where the B probe started (no earth), measure the time offset, this is the negative phase shift.
Frank