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Using a NTC to "charge" a supercap sounds to me like an error of reasoning. It's resistance drops within seconds maximum, but expected charging times are in a minute range, so what should it be good for?
NTCs are meaningful as current inrush limitation for rectifier filter capacitors, achievable time constants are in a 100 ms to a few seconds range. The important feature is that they stay at low resistance after charge phase to pass the regular operating current.
NTCs are meaningful as current inrush limitation for rectifier filter capacitors, achievable time constants are in a 100 ms to a few seconds range. The important feature is that they stay at low resistance after charge phase to pass the regular operating current.